A surface-enhanced Raman scattering study of CTAB adsorption on copper

Surface-enhanced Raman spectroscopy (SERS) has been used to study, in situ, the adsorption of cetyltrimethylammonium bromide (CTAB) on copper. The data obtained allow the determination of CTAB's adsorption rate from aqueous solution and are consistent with physisorption or weak chemisorption vi...

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Veröffentlicht in:Surface science 1983-12, Vol.134 (3), p.675-688
Hauptverfasser: Dendramis, A.L., Schwinn, E.W., Sperline, R.P.
Format: Artikel
Sprache:eng
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Zusammenfassung:Surface-enhanced Raman spectroscopy (SERS) has been used to study, in situ, the adsorption of cetyltrimethylammonium bromide (CTAB) on copper. The data obtained allow the determination of CTAB's adsorption rate from aqueous solution and are consistent with physisorption or weak chemisorption via the quaternary ammonium group. The use of “surface selection rules” to derive orientation information is examined.
ISSN:0039-6028
1879-2758
DOI:10.1016/0039-6028(83)90065-1