Electro-membrane extraction of cadmium(II) by bis(2-ethylhexyl) phosphate/kerosene/polyvinyl chloride polymer inclusion membrane

Highlights [Display omitted] The development of the electroplating and battery industries has increased the environmental problems and the needs for resource recovery of Cd(II). In this study, the Electro-membrane extraction (EME) behaviour of Cd(II) was investigated by using polymer inclusion membrane with bis(2-ethylhexyl) phosphate as carrier and polyvinyl chloride as base polymer(PD-PIM) at 0−80 V. Results showed that the EME of Cd(II) by PD-PIM can be obtained in the feed phase with pH 3–8 and stripping phase of dilute acid. Voltage is the main factor to increase the mass transfer rate of Cd(II). The applied electric field reduced the mass transfer activation energy of Cd(II) by PD-PIM and weakened the mass transfer interference of Cd(II) on the background material of the feed phase. After using kerosene-stabilised PD-PIM for operation at pH5, 60 V for 120 h, Cd(II) in the 1 L solution reduced from 15 mg/L to 0.08 mg/L, and the enrichment factor was 9.79.