Absolute configuration of chiral polar crystals

Absolute configuration of chiral polar crystals

A method is described for direct determination of absolute configuration of chiral polar crystals, based on changes in crystal habit induced by tailor-made impurities. The method embodies the assignment of the direction of the chiral substrate molecule with respect to the crystal polar axis based on...

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Veröffentlicht in:Nature (London) 1982-01, Vol.296 (5852), p.27-34
Hauptverfasser: Berkovitch-Yellin, Z, Addadi, L, Idelson, M, Leiserowitz, L, Lahav, M
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container_end_page 34
container_issue 5852
container_start_page 27
container_title Nature (London)
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creator Berkovitch-Yellin, Z
Addadi, L
Idelson, M
Leiserowitz, L
Lahav, M
description A method is described for direct determination of absolute configuration of chiral polar crystals, based on changes in crystal habit induced by tailor-made impurities. The method embodies the assignment of the direction of the chiral substrate molecule with respect to the crystal polar axis based on differences in the hemihedral faces of the substrate crystals as grown from solution in the presence and absence of impurities. The molecular packing requirements and the choice of impurities for application of this method in lysine and trans-cinnamoyl alanine are outlined.
doi_str_mv 10.1038/296027a0
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subjects Humanities and Social Sciences
multidisciplinary
Science
Science (multidisciplinary)
title Absolute configuration of chiral polar crystals
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