Hydrogenating effect of single-crystal diamond surface

Hydrogenation of diamond has been carried out using the electron-cyclotron-resonance microwave plasma chemical-vapor deposition apparatus. According to reflection high-energy and low-energy electron diffraction and X-ray photoelectron spectroscopy measurements, the natural- and synthetic-diamond surfaces maintained their crystallinity even after the hydrogenation. Seebeck effect measurement and the temperature dependence of the resistance revealed an appearance of deep acceptor levels in the hydrogenated diamond layer. The diffusion depth of the hydrogen by the plasma treatment (2 h, 830°C) was roughly estimated to be ∼0.6 µm from the drain current-voltage characteristics of a rudimentary MISFET using the hydrogenated diamond.