Exploring anomeric glycosylation of phosphoric acid: Optimisation and scope for non-native substrates

Exploring anomeric glycosylation of phosphoric acid: Optimisation and scope for non-native substrates

[Display omitted] •Glycosyl 1-phosphate chemical synthesis.•Anomeric phosphorylation of acetylated precursors.•Evaluation of glycosylation methodology to access native and modified glycosyl 1-phosphates.

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Veröffentlicht in:Carbohydrate research 2020-02, Vol.488, p.107896-107896, Article 107896
Hauptverfasser: Beswick, Laura, Ahmadipour, Sanaz, Hofman, Gert-Jan, Wootton, Hannah, Dimitriou, Eleni, Reynisson, Jóhannes, Field, Robert A., Linclau, Bruno, Miller, Gavin J.
Format: Artikel
Sprache:eng
Schlagworte:
Biochemistry & Molecular Biology
Chemistry
Chemistry, Applied
Chemistry, Organic
Glycosylation
Life Sciences & Biomedicine
Molecular Conformation
Molecular Structure
Phosphoric Acids - chemistry
Physical Sciences
Science & Technology
Stereoisomerism
Vacuum
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Beschreibung
Zusammenfassung:[Display omitted] •Glycosyl 1-phosphate chemical synthesis.•Anomeric phosphorylation of acetylated precursors.•Evaluation of glycosylation methodology to access native and modified glycosyl 1-phosphates.
ISSN:0008-6215
1873-426X
DOI:10.1016/j.carres.2019.107896