Influence of some physicochemical parameters on the passive sampling of copper (II) from aqueous medium using a polymer inclusion membrane device

Recently polymer inclusion membranes (PIMs) have been proposed as materials for passive sampling, nonetheless a theoretical base to describe the mass transfer process through those materials, under such conditions of monitoring, has not been elucidated. Under the assumption that: (i) the transport of the metal ion occurs at steady state conditions, (ii) the concentration gradients are linear, and (iii) the kinetics of the chemical reactions in the extraction process on the membrane are elemental; an equation for the passive sampling of copper (II) using a PIM system containing Kelex-100 as carrier is derived. The prediction capacity of this sampler under different conditions of temperature, metal concentration, flow velocity, ionic strength and pH is analyzed as well. Among the dependencies of the PIM on the physicochemical conditions, effects of concentration, temperature and flow velocity tend to increment copper (II) flux across the membrane, being the parameter temperature the one with the most pronounced effect at T ≥ 30 °C. Ionic strength had no great effect on passive sampler response, however the sampler is dependent on the acidity of the medium. The comparable metal ion concentrations estimated from the PIM sampler to those obtained by direct measurements of the sampling medium suggest that PIMs can be robust materials when used as passive sampler devices. [Display omitted] •A calibration equation was derived for the passive sampling of Cu (II) using PIMs.•Polymer membrane composition plays a fundamental role in passive sampling.•In static conditions a diffusional-kinetic process controlled the metal transport.•Passive sampler estimation accuracies had a dependence on temperature and pH. A calibration equation was derived for passive sampling of Cu (II) using PIMs and the influence of some parameters analyzed. Predictions agreed with direct measurements of the medium.