Ultralight, highly compressible, hydrophobic and anisotropic lamellar carbon aerogels from graphene/polyvinyl alcohol/cellulose nanofiber aerogel as oil removing absorbents

[Display omitted] •It is a bio-based carbon aerogel that is environmentally friendly.•The morphology could be controlled by using different freezing methods.•It could absorb oils and organic solvents up to 288 times of its own weight.•The carbon aerogels exhibited outstanding compressibility and recyclability. In increasingly serious marine pollution environment, environmentally friendly low-density aerogels have become potential oil-water separation materials. However, many reported aerogels have the drawbacks of low oil absorption, poor compressibility and flexibility, which limit their application. Herein, we reported a compressible, anisotropic lamellar hydrophobic and lipophilic graphene/polyvinyl alcohol/cellulose nanofiber carbon aerogel (a-GPCCA) prepared by directional freeze-drying and carbonization processes. The synthetic ultralight a-GPCCA had low density (6.17 mg/cm3) and high porosity (99.61 %). Moreover, directional freeze-drying resulted in a lamellar interpenetrated three-dimensional porous structure, which endowed it with high adsorption capacity (155–288 times of its weight), good compressibility (95 % recovery after repeating 15 cycles at 50 % strain in parallel to the freezing direction) and recyclability (oil retention rate reached 88.8 % after 10 absorption-compression cycles). Furthermore, carbonization provided it with excellent thermal stability and hydrophobic properties, resulting in oil-water selectivity and combustion cyclicity (the oil absorption capacity was reduced by only 10.2 % after 10 absorption-combustion cycles). Therefore, the a-GPCCA obtained in this study possesses a promising potential in the field of treatment of offshore oil spills and domestic industrial wastewater.