Trace element partitioning between ionic crystal and liquid

The partitioning of trace elements between ionic crystals and the melt has been correlated with lattice energy of the host. The solid-liquid partition coefficient has been expressed in terms of the difference in relative ionic radius of the trace element and the homogeneous and heterogeneous strain...

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Veröffentlicht in:The Journal of physics and chemistry of solids 1978, Vol.39 (4), p.439-442
Hauptverfasser: Tsang, T., Philpotts, J.A., Yin, L.
Format: Artikel
Sprache:eng
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Zusammenfassung:The partitioning of trace elements between ionic crystals and the melt has been correlated with lattice energy of the host. The solid-liquid partition coefficient has been expressed in terms of the difference in relative ionic radius of the trace element and the homogeneous and heterogeneous strain of the host lattice. Predictions based on this model appear to be in general agreement with data for alkali nitrates and for rare-earth elements in natural garnet phenocrysts.
ISSN:0022-3697
1879-2553
DOI:10.1016/0022-3697(78)90086-0