Simultaneous control of soil erosion and arsenic leaching at disturbed land using polyacrylamide modified magnetite nanoparticles

[Display omitted] •Prepared a new class of polyacrylamide-dispersed magnetite nanoparticles (PAM-MAG).•Tested PAM-MAG for simultaneous control of soil erosion and arsenic leaching from soil.•Surface application of PAM-MAG was able to decrease cumulative soil erosion by 90.8%.•The PAM-MAG treatment concurrently immobilized 82.5% of water-leachable arsenate.•Arsenate was immobilized by magnetite particles through surface complexation (Fe-O-As). Rapid urbanization and human disturbance of land often results in serious soil erosion and releases of fine sediments and soil-bound toxic metals/metalloids. Yet, technologies for simultaneously controlling soil erosion and metals/metalloids leaching have been lacking. This study developed a new class of polyacrylamide-dispersed magnetite (PAM-MAG) nanoparticles and tested the effectiveness for simultaneous control of soil erosion and arsenic leaching from a model soil. Two parallel box test setups (L × W × H: 91.4 × 30.5 × 7.6 cm) were constructed to test the releases of sediments and soluble pollutants from the surface soil under simulated rainfall conditions (intensity = 11.15 cm/hr). A sandy loam soil from a local quarry mining site was used as the model soil, and arsenate As(V) as a prototype leachable metalloid. A stable dispersion of PAM-MAG was prepared with 0.3 wt% of PAM and 0.1 g/L as Fe of magnetite. The results indicated that treating the soil with 5.985 g/m2 of PAM-MAG was able to decrease cumulative soil mass loss in the runoff by 90.8% (from 254.50 ± 0.10 g to 23.35 ± 3.19 g), or turbidity of the runoff by 79.9% (from 244.5 ± 27.5 NTU to 49.2 ± 22.5 NTU). Compared to PAM only, the PAM-MAG suspension showed a 30% reduction of viscosity, allowing for easier application and transport of the nanoparticles in soil. Concurrently, the PAM-MAG treatment also immobilized 82.5% of water-leachable arsenate compared to untreated controls. Fourier-transform infrared (FTIR) spectroscopy analyses revealed that arsenate was immobilized by magnetite nanoparticles through inner sphere surface complexation (Fe-O-As). Overall, the PAM-MAG based technology holds the promise for simultaneously controlling soil erosion and metal/metalloid releases from disturbed land.