Electronic Properties and the Lattice Instability of Laves-Phase ZrV sub 2

Pure, perfect, single-crystal ZrV sub 2 does not undergo a structural phase transformation but all other sample modifications, including twinned single crystal, do transform ( approx 100 deg K) from the cubic to a rhombohedral phase. All samples exhibit, in addition, an electronic instability (also...

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Veröffentlicht in:Physical review letters 1978-09, Vol.41 (13), p.899-903
Hauptverfasser: Levinson, M, Zahradnik, C, Bergh, R, MacVicar, M L A, Bostock, J
Format: Artikel
Sprache:eng
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Zusammenfassung:Pure, perfect, single-crystal ZrV sub 2 does not undergo a structural phase transformation but all other sample modifications, including twinned single crystal, do transform ( approx 100 deg K) from the cubic to a rhombohedral phase. All samples exhibit, in addition, an electronic instability (also approx 100 deg K). An anomaly in the ultrasonic velocity occurs at higher temp. ( approx 150-180 deg K) for pure polycrystalline ZrV sub 2 samples.28 refs.--AA
ISSN:0031-9007