Rhodium catalyzed C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

Rhodium catalyzed C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy. The tandem "conjugate addition/β-C cleavage/protonation" process (CCP) is reported.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-10, Vol.55 (84), p.1277-1271
Hauptverfasser: Yang, Xuan, Kong, Wei-Yu, Gao, Jia-Ni, Cheng, Li, Li, Nan-Nan, Li, Meng, Li, Hui-Ting, Fan, Jun, Gao, Jin-Ming, Ouyang, Qin, Xie, Jian-Bo
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Aromatic compounds
Cleavage
Coupling
Protonation
Rhodium
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Beschreibung
Zusammenfassung:The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy. The tandem "conjugate addition/β-C cleavage/protonation" process (CCP) is reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc06446j