Exploring the promising potential of MoS2–RuS2 binary metal sulphide towards the electrocatalysis of antibiotic drug sulphadiazine

Benefiting from the rich redox chemistry, high electrical conductivity and synergistic effect from two metal ions, the binary metal sulphides received tremendous attention in various applications. As a result, the MoS2–RuS2 nanomaterial was synthesized through the simple one-pot hydrothermal technique. The electrocatalytic activity of the as-synthesized nanomaterial was exploited towards the electrochemical detection of antibiotic drug sulphadiazine (SDZ). The electrocatalytic oxidation of the SDZ exhibited lowest anodic peak potential and ehanced anodic peak current rather than other modified electrodes. Notably, an excellent electrochemical performance with very lowest limit of detection (LOD) of 0.004 μM, appreciable linear range from 0.01 μM to 598.7 μM and high sensitivity (2.333 μA μM−1 cm−2) was obtained at MoS2–RuS2 modified electrode. Moreover, well anti-interfering property, good operational stability, repeatability and reproducibility was achieved. Facinatingly, the practicability of the modified electrode demonstrated in milk and human serum samples. [Display omitted] •The MoS2–RuS2 heterostructured nanomaterial was synthesized via one-pot hydrothermal synthesis.•The excellent electro catalytic activity was exploited towards the electrochemical detection of antibiotic drug SDZ.•The wide linear detection ranges from 0.01 μM to 598.7 μM with the LOD of 0.004 μM was achieved for the detection of SDZ.•The real-time application was demonstrated in milk and human serum samples.