Polymerizations Mediated by Well‐Defined Rhodium Complexes

This Minireview details the current state‐of‐the‐art relating to (co)polymerizations mediated by well‐defined RhI‐ethynyl, vinyl, and aryl complexes. In particular, we focus on RhI species suitable for the (co)polymerization of phenylacetylenes, arylisocyanides, as well as propargyl esters and amide...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-03, Vol.59 (13), p.5008-5021
Hauptverfasser:	Tan, Nicholas Sheng Loong, Lowe, Andrew B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Aromatic compounds arylisocyanides Chemistry Chemistry, Multidisciplinary controlled polymerization Esters Physical Sciences Polymerization polyphenylacetylenes Rhodium rhodium complexes Science & Technology stereoregularity
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Beschreibung
Zusammenfassung:	This Minireview details the current state‐of‐the‐art relating to (co)polymerizations mediated by well‐defined RhI‐ethynyl, vinyl, and aryl complexes. In particular, we focus on RhI species suitable for the (co)polymerization of phenylacetylenes, arylisocyanides, as well as propargyl esters and amides. Rhodium chains: This Minireview details the current state‐of‐the‐art relating to (co)polymerizations mediated by well‐defined RhI‐ethynyl, vinyl, and aryl complexes. The focus is on RhI species suitable for the (co)polymerization of phenylacetylenes, arylisocyanides, as well as propargyl esters and amides.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201909909