Promoting Oxygen Evolution Reaction of Co‐Based Catalysts (Co3O4, CoS, CoP, and CoN) through Photothermal Effect

The increase of reaction temperature of electrocatalysts is regarded as an efficient method to improve the oxygen evolution reaction (OER) activity. Herein, it is reported that the electrocatalytic performance of dual functional (i.e., electrocatalytic and photothermal functions) Co3O4 can be dramatically improved via its photothermal effect. The operating temperature of the Co3O4 electrode is elevated in situ under near infrared (NIR) light irradiation, resulting in enhanced oxygen evolution activity due to its accelerated electrical conductivity, reaction kinetics, and desorption rate of O2 bubbles from the electrode. In addition, photothermal effect can also enhance the electrocatalytic reaction rates of metal‐doped Co3O4 electrodes, indicating that it is able to significantly improve the OER activities of electrodes together with other modification strategies. With the assistance of the photothermal effect, the obtained Ni‐doped Co3O4 catalyst requires an extremely low overpotential of 208 mV to achieve a benchmark of 10 mA cm−2 with a small Tafel slope, superior to most reported Co‐based catalysts. Significantly, the electrocatalytic performance of other electrodes with photothermal effect, such as CoN, CoP, and CoS, are also boosted under NIR light irradiation, indicating opportunities for implementing photothermal enhancement in electrocatalytic water splitting. The electrocatalytic water oxidation performance of Co‐based catalysts (Co3O4, CoS, CoP, and CoN) are significantly promoted via the photothermal effect. The operating temperature of a Co3O4 electrode is elevated in situ under near infrared (NIR) light irradiation, resulting in enhanced oxygen evolution activity due to accelerated electrical conductivity, reaction kinetics, and the desorption rate of O2 bubbles from the electrode.