Enhancement of effective polar anchoring strength and accelerated electro-optic switching in a two-dimensional hexagonal boron nitride/polyimide hybrid liquid crystal device

The monolayer hexagonal boron nitride (h-BN) nanosheet is transferred onto an indium tin oxide (ITO)-coated glass substrate. This h-BN slide is placed together with a conventional planar-aligning polyimide (PI) slide to fabricate a liquid crystal (LC) cell, in which the LC achieves uniform planar alignment. The effective polar anchoring strength coefficient of this h-BN-based hybrid LC device is found to increase significantly compared to that of a standard PI/PI LC device. The presence of the monolayer h-BN nanosheet as an alignment agent increases the planar anchoring energy through the epitaxial interaction between the LC and the honeycomb structure of the two-dimensional h-BN lattice in this hybrid device. The amplified polar anchoring energy is found to accelerate the electro-optic response time of the LC in this h-BN-based hybrid device.