C-H and N-H bond annulation of aryl amides with unactivated olefins by merging cobalt() and photoredox catalysis

C-H and N-H bond annulation of aryl amides with unactivated olefins by merging cobalt() and photoredox catalysis

A mild, environment-friendly protocol has been developed to carry out the [4+2] annulation of aryl amides with unactivated olefins. A range of sterically and electronically diverse aryl amides and unactivated olefins were successfully employed under the developed conditions to get a variety of dihyd...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-09, Vol.55 (77), p.11626-11629
Hauptverfasser: Kalsi, Deepti, Barsu, Nagaraju, Chakrabarti, Sagnik, Dahiya, Pardeep, Rueping, Magnus, Sundararaju, Basker
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Amides
Aromatic compounds
Chemical reactions
Hydrogen bonds
Organic chemistry
Photoredox catalysis
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Beschreibung
Zusammenfassung:A mild, environment-friendly protocol has been developed to carry out the [4+2] annulation of aryl amides with unactivated olefins. A range of sterically and electronically diverse aryl amides and unactivated olefins were successfully employed under the developed conditions to get a variety of dihydroisoquinolinones in good-to-excellent yields. A mild, environment-friendly protocol has been developed to carry out the [4+2] annulation of aryl amides with unactivated olefins.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc05744g