Transient Light‐Emitting Diodes Constructed from Semiconductors and Transparent Conductors that Biodegrade Under Physiological Conditions

Transient forms of electronics, systems that disintegrate, dissolve, resorb, or sublime in a controlled manner after a well‐defined operating lifetime, are of interest for applications in hardware secure technologies, temporary biomedical implants, “green” consumer devices and other areas that cannot be addressed with conventional approaches. Broad sets of materials now exist for a range of transient electronic components, including transistors, diodes, antennas, sensors, and even batteries. This work reports the first examples of transient light‐emitting diodes (LEDs) that can completely dissolve in aqueous solutions to biologically and environmentally benign end products. Thin films of highly textured ZnO and polycrystalline Mo serve as semiconductors for light generation and conductors for transparent electrodes, respectively. The emitted light spans a range of visible wavelengths, where nanomembranes of monocrystalline silicon can serve as transient filters to yield red, green, and blue LEDs. Detailed characterization of the material chemistries and morphologies of the constituent layers, assessments of their performance properties, and studies of their dissolution processes define the underlying aspects. These results establish an electroluminescent light source technology for unique classes of optoelectronic systems that vanish into benign forms when exposed to aqueous conditions in the environment or in living organisms. Light‐emitting diodes constructed from biodegradable materials—ZnO as a direct bandgap semiconductor and Mo as semitransparent ultrathin electrodes—convert electrical power into light, in a platform that dissolves completely in aqueous solutions to biologically and environmentally benign end products. Such systems pave the way toward applications that cannot be addressed with conventional optoelectronic technologies, such as temporary medical implants and environmentally friendly displays.