Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems

Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems

In a previous article, it was reported that a rather amount of sulfate end-groups as initiator fragment were buried in the inside of polystyrene (PS) particles, which were synthesized by emulsion polymerization with potassium persulfate initiator and nonionic emulsifier and operated to absorb water...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Langmuir 2019-09, Vol.35 (37), p.12150-12157
Hauptverfasser: Shi, Hao, Huang, Chujuan, Liu, Xiang, Okubo, Masayoshi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 12157
container_issue 37
container_start_page 12150
container_title Langmuir
container_volume 35
creator Shi, Hao
Huang, Chujuan
Liu, Xiang
Okubo, Masayoshi
description In a previous article, it was reported that a rather amount of sulfate end-groups as initiator fragment were buried in the inside of polystyrene (PS) particles, which were synthesized by emulsion polymerization with potassium persulfate initiator and nonionic emulsifier and operated to absorb water from the aqueous medium, resulting in hollow particles, when the PS emulsion was treated at higher temperature than the glass transition temperature of PS. In this article, it was clarified that the water absorption is based on the osmotic pressure between the outside (aqueous medium) and inside of the PS particles due to the buried sulfate end-groups.
doi_str_mv 10.1021/acs.langmuir.9b01952
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2280567455</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2280567455</sourcerecordid><originalsourceid>FETCH-LOGICAL-a385t-575ac7ce41637106259ef046eb775b581487d79efca05b3372277d514bd06a533</originalsourceid><addsrcrecordid>eNp9kc1u1DAUhS1URIfCG6DKyy7I4N84WVYtwyBV6ogp68hJblpXcTz1dYSGl-CV8WimLNn4StZ3zv05hHzibMmZ4F9sh8vRTo9-dnFZt4zXWrwhC64FK3QlzBlZMKNkYVQpz8l7xGfGWC1V_Y6cS65UVfJ6Qf78CCPQMNB79CG5jm4iIM4R6BAiTU9AVyF6m1yYDtR2bgvvuhg8JIjF1v2G_jNdh3EMv-gmjHtM-wgT0I2N2W0EpO2ersEm-hDz62FK1E30-mWGMCO9dbiDiNDTbZaCxw_k7WBHhI-nekF-rr4-3KyLu_tv32-u7worK50KbbTtTAeKl9JwVgpdw8BUCa0xutUVV5XpTf7rLNOtlEYIY3rNVduz0mopL8jV0XcXQ54FU-MddjDmix4Ga4SomC6N0jqj6ojmtREjDM0uOm_jvuGsOUTR5Cia1yiaUxRZdnnqMLce-n-i19tngB2Bg_w5zHHKC__f8y-YH5qU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2280567455</pqid></control><display><type>article</type><title>Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems</title><source>ACS Publications</source><creator>Shi, Hao ; Huang, Chujuan ; Liu, Xiang ; Okubo, Masayoshi</creator><creatorcontrib>Shi, Hao ; Huang, Chujuan ; Liu, Xiang ; Okubo, Masayoshi</creatorcontrib><description>In a previous article, it was reported that a rather amount of sulfate end-groups as initiator fragment were buried in the inside of polystyrene (PS) particles, which were synthesized by emulsion polymerization with potassium persulfate initiator and nonionic emulsifier and operated to absorb water from the aqueous medium, resulting in hollow particles, when the PS emulsion was treated at higher temperature than the glass transition temperature of PS. In this article, it was clarified that the water absorption is based on the osmotic pressure between the outside (aqueous medium) and inside of the PS particles due to the buried sulfate end-groups.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/acs.langmuir.9b01952</identifier><identifier>PMID: 31448619</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Langmuir, 2019-09, Vol.35 (37), p.12150-12157</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a385t-575ac7ce41637106259ef046eb775b581487d79efca05b3372277d514bd06a533</citedby><cites>FETCH-LOGICAL-a385t-575ac7ce41637106259ef046eb775b581487d79efca05b3372277d514bd06a533</cites><orcidid>0000-0003-1189-572X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.langmuir.9b01952$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.langmuir.9b01952$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31448619$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shi, Hao</creatorcontrib><creatorcontrib>Huang, Chujuan</creatorcontrib><creatorcontrib>Liu, Xiang</creatorcontrib><creatorcontrib>Okubo, Masayoshi</creatorcontrib><title>Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>In a previous article, it was reported that a rather amount of sulfate end-groups as initiator fragment were buried in the inside of polystyrene (PS) particles, which were synthesized by emulsion polymerization with potassium persulfate initiator and nonionic emulsifier and operated to absorb water from the aqueous medium, resulting in hollow particles, when the PS emulsion was treated at higher temperature than the glass transition temperature of PS. In this article, it was clarified that the water absorption is based on the osmotic pressure between the outside (aqueous medium) and inside of the PS particles due to the buried sulfate end-groups.</description><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u1DAUhS1URIfCG6DKyy7I4N84WVYtwyBV6ogp68hJblpXcTz1dYSGl-CV8WimLNn4StZ3zv05hHzibMmZ4F9sh8vRTo9-dnFZt4zXWrwhC64FK3QlzBlZMKNkYVQpz8l7xGfGWC1V_Y6cS65UVfJ6Qf78CCPQMNB79CG5jm4iIM4R6BAiTU9AVyF6m1yYDtR2bgvvuhg8JIjF1v2G_jNdh3EMv-gmjHtM-wgT0I2N2W0EpO2ersEm-hDz62FK1E30-mWGMCO9dbiDiNDTbZaCxw_k7WBHhI-nekF-rr4-3KyLu_tv32-u7worK50KbbTtTAeKl9JwVgpdw8BUCa0xutUVV5XpTf7rLNOtlEYIY3rNVduz0mopL8jV0XcXQ54FU-MddjDmix4Ga4SomC6N0jqj6ojmtREjDM0uOm_jvuGsOUTR5Cia1yiaUxRZdnnqMLce-n-i19tngB2Bg_w5zHHKC__f8y-YH5qU</recordid><startdate>20190917</startdate><enddate>20190917</enddate><creator>Shi, Hao</creator><creator>Huang, Chujuan</creator><creator>Liu, Xiang</creator><creator>Okubo, Masayoshi</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1189-572X</orcidid></search><sort><creationdate>20190917</creationdate><title>Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems</title><author>Shi, Hao ; Huang, Chujuan ; Liu, Xiang ; Okubo, Masayoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a385t-575ac7ce41637106259ef046eb775b581487d79efca05b3372277d514bd06a533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shi, Hao</creatorcontrib><creatorcontrib>Huang, Chujuan</creatorcontrib><creatorcontrib>Liu, Xiang</creatorcontrib><creatorcontrib>Okubo, Masayoshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shi, Hao</au><au>Huang, Chujuan</au><au>Liu, Xiang</au><au>Okubo, Masayoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2019-09-17</date><risdate>2019</risdate><volume>35</volume><issue>37</issue><spage>12150</spage><epage>12157</epage><pages>12150-12157</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><abstract>In a previous article, it was reported that a rather amount of sulfate end-groups as initiator fragment were buried in the inside of polystyrene (PS) particles, which were synthesized by emulsion polymerization with potassium persulfate initiator and nonionic emulsifier and operated to absorb water from the aqueous medium, resulting in hollow particles, when the PS emulsion was treated at higher temperature than the glass transition temperature of PS. In this article, it was clarified that the water absorption is based on the osmotic pressure between the outside (aqueous medium) and inside of the PS particles due to the buried sulfate end-groups.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>31448619</pmid><doi>10.1021/acs.langmuir.9b01952</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-1189-572X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0743-7463
ispartof Langmuir, 2019-09, Vol.35 (37), p.12150-12157
issn 0743-7463
1520-5827
language eng
recordid cdi_proquest_miscellaneous_2280567455
source ACS Publications
title Role of Osmotic Pressure for the Formation of Sub-micrometer-Sized, Hollow Polystyrene Particles by Heat Treatment in Aqueous Dispersed Systems
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T04%3A25%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Role%20of%20Osmotic%20Pressure%20for%20the%20Formation%20of%20Sub-micrometer-Sized,%20Hollow%20Polystyrene%20Particles%20by%20Heat%20Treatment%20in%20Aqueous%20Dispersed%20Systems&rft.jtitle=Langmuir&rft.au=Shi,%20Hao&rft.date=2019-09-17&rft.volume=35&rft.issue=37&rft.spage=12150&rft.epage=12157&rft.pages=12150-12157&rft.issn=0743-7463&rft.eissn=1520-5827&rft_id=info:doi/10.1021/acs.langmuir.9b01952&rft_dat=%3Cproquest_cross%3E2280567455%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2280567455&rft_id=info:pmid/31448619&rfr_iscdi=true