Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes

Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes

Most studies of ruthenium polypyridine complexes are devoted to their cis isomers. The fact that cis isomers are thermally more stable and thus easier to synthesize has prevented researchers from investigating the properties and applications of trans complexes. We present a study of thermal and phot...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2019-09, Vol.58 (17), p.11606-11613
Hauptverfasser: Rojas Pérez, Yeraldith, Slep, Leonardo D, Etchenique, Roberto
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 11613
container_issue 17
container_start_page 11606
container_title Inorganic chemistry
container_volume 58
creator Rojas Pérez, Yeraldith
Slep, Leonardo D
Etchenique, Roberto
description Most studies of ruthenium polypyridine complexes are devoted to their cis isomers. The fact that cis isomers are thermally more stable and thus easier to synthesize has prevented researchers from investigating the properties and applications of trans complexes. We present a study of thermal and photochemical cis–trans interconversion of the key complex [Ru­(bpy)2(PMe3)­(H2O)]2+ (bpy = 2,2′-bipyridine, PMe3 = trimethylphosphine), which results in specific synthetic applications of the trans species, potentially useful as a platform for designing highly efficient visible light activated caged compounds. We show, as a proof of concept, some examples of trans complexes bearing N-donor and P-donor ligands and their comparison with the cis isomers.
doi_str_mv 10.1021/acs.inorgchem.9b01485
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2275260734</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2275260734</sourcerecordid><originalsourceid>FETCH-LOGICAL-a398t-8917dd24d5cd31beb1ef6ad8da0ddd46cb9a1ed9bad2cf8827323b344d1ed8953</originalsourceid><addsrcrecordid>eNqFkMtOwzAQRS0EoqXwCaAsyyLFjzzsZYl4RKqEhIrELnJih7pK7GAniO74B_6QL8FVS7esZjS6947uAeASwRmCGN3wys2UNvatWsl2xkqIIhofgTGKMQxjBF-PwRhCv6MkYSNw5twaQshIlJyCEUERojiBYzDPlPv5-l5arl2Q617ayugPaZ0yOlA6eB76ldRqaKd5fh3cqm5jlVBaBplpu0Z-SncOTmreOHmxnxPwcn-3zB7DxdNDns0XISeM9iFlKBUCRyKuBEGlLJGsEy6o4FAIESVVyTiSgpVc4KqmFKcEk5JEkfBXymIyAdNdbmfN-yBdX7TKVbJpuJZmcAXGaewrpSTy0ngnraxxzsq66Kxqud0UCBZbeoWnVxzoFXt63ne1fzGUrRQH1x8uL0A7wda_NoPVvvE_ob8jY4HK</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2275260734</pqid></control><display><type>article</type><title>Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes</title><source>ACS Publications</source><creator>Rojas Pérez, Yeraldith ; Slep, Leonardo D ; Etchenique, Roberto</creator><creatorcontrib>Rojas Pérez, Yeraldith ; Slep, Leonardo D ; Etchenique, Roberto</creatorcontrib><description>Most studies of ruthenium polypyridine complexes are devoted to their cis isomers. The fact that cis isomers are thermally more stable and thus easier to synthesize has prevented researchers from investigating the properties and applications of trans complexes. We present a study of thermal and photochemical cis–trans interconversion of the key complex [Ru­(bpy)2(PMe3)­(H2O)]2+ (bpy = 2,2′-bipyridine, PMe3 = trimethylphosphine), which results in specific synthetic applications of the trans species, potentially useful as a platform for designing highly efficient visible light activated caged compounds. We show, as a proof of concept, some examples of trans complexes bearing N-donor and P-donor ligands and their comparison with the cis isomers.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.9b01485</identifier><identifier>PMID: 31418260</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2019-09, Vol.58 (17), p.11606-11613</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a398t-8917dd24d5cd31beb1ef6ad8da0ddd46cb9a1ed9bad2cf8827323b344d1ed8953</citedby><cites>FETCH-LOGICAL-a398t-8917dd24d5cd31beb1ef6ad8da0ddd46cb9a1ed9bad2cf8827323b344d1ed8953</cites><orcidid>0000-0002-5485-8710 ; 0000-0001-6447-2216</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.9b01485$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01485$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2764,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31418260$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rojas Pérez, Yeraldith</creatorcontrib><creatorcontrib>Slep, Leonardo D</creatorcontrib><creatorcontrib>Etchenique, Roberto</creatorcontrib><title>Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Most studies of ruthenium polypyridine complexes are devoted to their cis isomers. The fact that cis isomers are thermally more stable and thus easier to synthesize has prevented researchers from investigating the properties and applications of trans complexes. We present a study of thermal and photochemical cis–trans interconversion of the key complex [Ru­(bpy)2(PMe3)­(H2O)]2+ (bpy = 2,2′-bipyridine, PMe3 = trimethylphosphine), which results in specific synthetic applications of the trans species, potentially useful as a platform for designing highly efficient visible light activated caged compounds. We show, as a proof of concept, some examples of trans complexes bearing N-donor and P-donor ligands and their comparison with the cis isomers.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EoqXwCaAsyyLFjzzsZYl4RKqEhIrELnJih7pK7GAniO74B_6QL8FVS7esZjS6947uAeASwRmCGN3wys2UNvatWsl2xkqIIhofgTGKMQxjBF-PwRhCv6MkYSNw5twaQshIlJyCEUERojiBYzDPlPv5-l5arl2Q617ayugPaZ0yOlA6eB76ldRqaKd5fh3cqm5jlVBaBplpu0Z-SncOTmreOHmxnxPwcn-3zB7DxdNDns0XISeM9iFlKBUCRyKuBEGlLJGsEy6o4FAIESVVyTiSgpVc4KqmFKcEk5JEkfBXymIyAdNdbmfN-yBdX7TKVbJpuJZmcAXGaewrpSTy0ngnraxxzsq66Kxqud0UCBZbeoWnVxzoFXt63ne1fzGUrRQH1x8uL0A7wda_NoPVvvE_ob8jY4HK</recordid><startdate>20190903</startdate><enddate>20190903</enddate><creator>Rojas Pérez, Yeraldith</creator><creator>Slep, Leonardo D</creator><creator>Etchenique, Roberto</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5485-8710</orcidid><orcidid>https://orcid.org/0000-0001-6447-2216</orcidid></search><sort><creationdate>20190903</creationdate><title>Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes</title><author>Rojas Pérez, Yeraldith ; Slep, Leonardo D ; Etchenique, Roberto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a398t-8917dd24d5cd31beb1ef6ad8da0ddd46cb9a1ed9bad2cf8827323b344d1ed8953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rojas Pérez, Yeraldith</creatorcontrib><creatorcontrib>Slep, Leonardo D</creatorcontrib><creatorcontrib>Etchenique, Roberto</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rojas Pérez, Yeraldith</au><au>Slep, Leonardo D</au><au>Etchenique, Roberto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2019-09-03</date><risdate>2019</risdate><volume>58</volume><issue>17</issue><spage>11606</spage><epage>11613</epage><pages>11606-11613</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Most studies of ruthenium polypyridine complexes are devoted to their cis isomers. The fact that cis isomers are thermally more stable and thus easier to synthesize has prevented researchers from investigating the properties and applications of trans complexes. We present a study of thermal and photochemical cis–trans interconversion of the key complex [Ru­(bpy)2(PMe3)­(H2O)]2+ (bpy = 2,2′-bipyridine, PMe3 = trimethylphosphine), which results in specific synthetic applications of the trans species, potentially useful as a platform for designing highly efficient visible light activated caged compounds. We show, as a proof of concept, some examples of trans complexes bearing N-donor and P-donor ligands and their comparison with the cis isomers.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>31418260</pmid><doi>10.1021/acs.inorgchem.9b01485</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5485-8710</orcidid><orcidid>https://orcid.org/0000-0001-6447-2216</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2019-09, Vol.58 (17), p.11606-11613
issn 0020-1669
1520-510X
language eng
recordid cdi_proquest_miscellaneous_2275260734
source ACS Publications
title Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T11%3A16%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cis%E2%80%93Trans%20Interconversion%20in%20Ruthenium(II)%20Bipyridine%20Complexes&rft.jtitle=Inorganic%20chemistry&rft.au=Rojas%20Pe%CC%81rez,%20Yeraldith&rft.date=2019-09-03&rft.volume=58&rft.issue=17&rft.spage=11606&rft.epage=11613&rft.pages=11606-11613&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.9b01485&rft_dat=%3Cproquest_cross%3E2275260734%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2275260734&rft_id=info:pmid/31418260&rfr_iscdi=true