Functional Materials for Two‐Photon Polymerization in Microfabrication

Direct laser writing methods based on two‐photon polymerization (2PP) are powerful tools for the on‐demand printing of precise and complex 3D architectures at the micro and nanometer scale. While much progress was made to increase the resolution and the feature size throughout the years, by carefully designing a material, one can confer specific functional properties to the printed structures thus making them appealing for peculiar and novel applications. This Review summarizes the state‐of‐the‐art of functional resins and photoresists used in 2PP, discussing both the range of material functions available and the methods used to prepare them, highlighting advantages and disadvantages of different classes of materials in achieving certain properties. Two‐photon polymerization (2PP) is a powerful tool for the on‐demand printing of precise and complex 3D architectures at the micro and nanometer scale. This Review summarizes the state‐of‐the‐art of functional resins and photoresists used in 2PP, discussing both the range of material functions available and the methods used to prepare them, highlighting advantages and disadvantages of different classes of materials in achieving certain properties.