Flexible Foil of Hybrid TaS2/Organic Superlattice: Fabrication and Electrical Properties

TaS2 nanolayers with reduced dimensionality show interesting physics, such as a gate‐tunable phase transition and enhanced superconductivity, among others. Here, a solution‐based strategy to fabricate a large‐area foil of hybrid TaS2/organic superlattice, where [TaS2] monolayers and organic molecules alternatively stack in atomic scale, is proposed. The [TaS2] layers are spatially isolated with remarkably weakened interlayer bonding, resulting in lattice vibration close to that of TaS2 monolayers. The foil also shows excellent mechanical flexibility together with a large electrical conductivity of 1.2 × 103 S cm−1 and an electromagnetic interference of 31 dB, among the highest values for solution‐processed thin films of graphene and inorganic graphene analogs. The solution‐based strategy reported herein can add a new dimension to manipulate the structure and properties of 2D materials and provide new opportunities for flexible nanoelectronic devices. A size‐tailorable foil of TaS2/organic superlattice is prepared by a solution‐based strategy. The lattice vibrations of the organics separated [TaS2] layers are close to that of single‐layered TaS2. The foil exhibits excellent flexibility, a large electrical conductivity of 1.2 × 103 S cm−1, and an electromagnetic interference of 31 dB.