Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N2O2- and N2O4-type dipyrrins

The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline e...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2019, Vol.48 (35), p.13169-13175
Hauptverfasser:	Sumiyoshi, Akinobu, Chiba, Yusuke, Matsuoka, Ryota, Noda, Takumu, Nabeshima, Tatsuya
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaline earth metals Crystallography Emission spectra Fluorescence Gallium Nitrogen tetroxide NMR Nuclear magnetic resonance Optical properties Titration
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Zusammenfassung:	The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline earth metal ions.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/c9dt02403d