Size-Selective Synthesis of Large Cycloparaphenyleneacetylene Carbon Nanohoops Using Alkyne Metathesis

Size selective synthesis of large cycloparaphenyleneacetylene carbon nanohoops was achieved using alkyne metathesis. The large nanohoops were stable in ambient conditions due to their reduced strain. The nanohoops exhibited blue fluorescence with high quantum yields.

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Veröffentlicht in:Organic letters 2019-06, Vol.21 (12), p.4680-4683
Hauptverfasser: Zhou, Xin, Thompson, Richard R, Fronczek, Frank R, Lee, Semin
Format: Artikel
Sprache:eng
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Zusammenfassung:Size selective synthesis of large cycloparaphenyleneacetylene carbon nanohoops was achieved using alkyne metathesis. The large nanohoops were stable in ambient conditions due to their reduced strain. The nanohoops exhibited blue fluorescence with high quantum yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.9b01563