KNa4B2P3O13: A Deep-Ultraviolet Transparent Borophosphate Exhibiting Second-Harmonic Generation Response
A new deep-ultraviolet transparent alkali metal borophosphate KNa4B2P3O13 is synthesized by high-temperature flux method, and its properties were characterized by a combination of experimental and ab initio methods. This compound crystallizes in the noncentrosymmetric Pna21 space group and its frame...
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| Veröffentlicht in: | Inorganic chemistry 2019-07, Vol.58 (14), p.8918-8921 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A new deep-ultraviolet transparent alkali metal borophosphate KNa4B2P3O13 is synthesized by high-temperature flux method, and its properties were characterized by a combination of experimental and ab initio methods. This compound crystallizes in the noncentrosymmetric Pna21 space group and its framework is formed of one-dimensional infinite [B2P3O13]∞ chains consisting of apex-sharing [BO4] and [PO4] tetrahedra. KNa4B2P3O13 had a short ultraviolet edge ( |
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| ISSN: | 0020-1669 1520-510X |
| DOI: | 10.1021/acs.inorgchem.9b01198 |