Nanohybrid carbon black-molybdenum disulfide transducers for preconcentration-free voltammetric detection of the olive oil o-diphenols hydroxytyrosol and oleuropein

A new hybrid nanomaterial is used in a screen-printed electrode (SPE) for sensing of the ortho-diphenols oleuropein (OLEU) and hydroxytyrosol (HYT) in extra virgin olive oil (EVOO) and related samples. The hybrid material consists of carbon black (CB) and molybdenum disulfide (MoS 2 ). In comparison with individual nanomaterials, CB-MoS 2 exhibits improved charge-transfer ability, low charge-transfer resistance, high electrical conductivity and enhanced electrocatalysis. The sensor is also characterized by (a) high sensitivity that avoids the need for adsorptive voltammetry, (b) reduced analysis time, and (c) high anti-fouling ability (electrode RSD OLEU