MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure
MX-type one-dimensional complexes [Pt IV (amp) 2 Br 2 ][Pt II/IV (amp) 2 Br] 2 (HSO 4 ) 2 (SO 4 ) 2 ·13H 2 O ( 3 ) and [Pt IV (amp) 2 Br 2 ][Pt II/IV (amp) 2 Br] 2 (H 2 PO 4 ) 6 ·8H 2 O ( 4 ) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt-Br chain structur...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-06, Vol.48 (22), p.7828-7834 |
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| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | MX-type one-dimensional complexes [Pt
IV
(amp)
2
Br
2
][Pt
II/IV
(amp)
2
Br]
2
(HSO
4
)
2
(SO
4
)
2
·13H
2
O (
3
) and [Pt
IV
(amp)
2
Br
2
][Pt
II/IV
(amp)
2
Br]
2
(H
2
PO
4
)
6
·8H
2
O (
4
) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt-Br chain structures of
3
and
4
are stabilized by both the hydrogen-bond network along the chain and the π-stacking
via
intercalated Pt(
iv
) complexes. Structural and spectroscopic studies indicated that both
3
and
4
form the Pt(
ii
/
iv
) mixed valence state.
MX-type one-dimensional complexes containing only an aromatic in-plane ligand were synthesized for the first time. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c9dt00784a |