Formation of a Supramolecular Polymeric Adhesive via Water–Participant Hydrogen Bond Formation

Formation of a Supramolecular Polymeric Adhesive via Water–Participant Hydrogen Bond Formation

A supra­molecular polymeric adhesive was prepared from non-viscous, non-polymeric materials by water–participant hydrogen bonds. Pt–pyridine coordination and water–crown ether hydrogen bonding combine to effect the supra­molecular polymerization. The supra­molecular polymeric adhesive displays stron...

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Veröffentlicht in:Journal of the American Chemical Society 2019-05, Vol.141 (20), p.8058-8063
Hauptverfasser: Zhang, Qiao, Li, Tao, Duan, Abing, Dong, Shengyi, Zhao, Wanxiang, Stang, Peter J
Format: Artikel
Sprache:eng
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Zusammenfassung:A supra­molecular polymeric adhesive was prepared from non-viscous, non-polymeric materials by water–participant hydrogen bonds. Pt–pyridine coordination and water–crown ether hydrogen bonding combine to effect the supra­molecular polymerization. The supra­molecular polymeric adhesive displays strong, reversible adhesion to hydrophilic surfaces, a property that forecasts the application of hydrogen bonding in advanced supra­molecular materials.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.9b02677