Ligand-Free, Quinoline N‑Assisted Copper-Catalyzed Nitrene Transfer Reaction To Synthesize 8‑Quinolylsulfimides

Ligand-Free, Quinoline N‑Assisted Copper-Catalyzed Nitrene Transfer Reaction To Synthesize 8‑Quinolylsulfimides

An efficient copper-catalyzed, quinolyl N-directed nitrene transfer reaction to 8-quinolylsulfides was described. A variety of 8-quinolylsulfimides with different functional groups were synthesized in moderate to high yields. The obtained 8-quinolylsulfimides were proved to be promising novel type o...

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Veröffentlicht in:Journal of organic chemistry 2019-06, Vol.84 (12), p.7618-7629
Hauptverfasser: Xiao, Xinsheng, Huang, Sanping, Tang, Shanshan, Jia, Guokai, Ou, Guangchuan, Li, Yangyan
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient copper-catalyzed, quinolyl N-directed nitrene transfer reaction to 8-quinolylsulfides was described. A variety of 8-quinolylsulfimides with different functional groups were synthesized in moderate to high yields. The obtained 8-quinolylsulfimides were proved to be promising novel type of bidentate ligands in Pd­(II)-catalyzed allylic alkylation.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.9b00281