Male workers' exposure characteristics of ΣPCDD/F from a municipal solid waste incinerator in south China through hair analysis

Human hair, flue gas and fly ash from a municipal solid waste incinerator (MSWI) in south China were collected and analyzed for polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF). The ΣPCDD/F level in hair from male workers were higher than those from residents. The Principal Component Analysis (PCA) suggested that ΣPCDD/F in flue gas is an external source of male workers' hair ΣPCDD/F. Results of daily intake of ΣPCDD/F by inhaling flue gas suggested that the inhalation exposure of ΣPCDD/F was at a slight health risk. For the male workers directly exposed to the MSWI power plant, ΣPCDD/F levels in their hair were significantly higher than those who were non-directly exposed. Moreover, a significantly positive relationship was obtained between ΣPCDD/F levels in male workers' hair and the working time. The result of correlation analysis suggested that 1,2,3,4,6,7,8-HpCDD and OCDD could be level indicator congeners to estimate ΣPCDD/F levels. In addition, 2,3,7,8-TCDD could be applied as TEQ indicator congener to characterize the hair of MSWI male workers. [Display omitted] •Different occupations had different influences on workers' hair ΣPCDD/F levels.•The inhalation exposure of ΣPCDD/F in flue gas was at a slight health risk.•The hair ΣPCDD/F levels were positively correlated with the working time.•1,2,3,4,6,7,8-HpCDD and OCDD were the ΣPCDD/F level indicators in hair.•2,3,7,8-TCDD was the ΣPCDD/F TEQ indicator in hair.