Catalytic co-pyrolysis of sugarcane bagasse and waste high-density polyethylene over faujasite-type zeolite
[Display omitted] •Catalytic co-pyrolysis of sugarcane bagasse with waste plastic was investigated.•Mesoporous faujasite-type zeolite from electric arc furnace slag was prepared.•Hydrocarbon production was greatly enhanced with 74.55% selectivity.•Oxygenate content was considerably decreased with 1....
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Veröffentlicht in: | Bioresource technology 2019-07, Vol.284, p.406-414 |
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Sprache: | eng |
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•Catalytic co-pyrolysis of sugarcane bagasse with waste plastic was investigated.•Mesoporous faujasite-type zeolite from electric arc furnace slag was prepared.•Hydrocarbon production was greatly enhanced with 74.55% selectivity.•Oxygenate content was considerably decreased with 1.24% selectivity.
This study investigated the catalytic co-pyrolysis of sugarcane bagasse (SCB) and waste high-density polyethylene (HDPE) over faujasite-type zeolite derived from electric arc furnace slag (FAU-EAFS) in a fixed-bed reactor. The effects of reaction temperature, catalyst-to-feedstock ratio, and HDPE-to-SCB ratio on product fractional yields and chemical compositions were discussed. The co-pyrolysis of SCB and HDPE over FAU-EAFS increased the liquid yield and enhanced the quality of bio-oil. The maximum bio-oil (68.56 wt%) and hydrocarbon yield (74.55%) with minimum yield of oxygenated compounds (acid = 0.57% and ester = 0.67%) were achieved under the optimum experimental conditions of catalyst-to-feedstock ratio of 1:6, HDPE-to-SCB ratio of 40:60, and temperature of 500 °C. The oil produced by catalytic co-pyrolysis had higher calorific value than the oil produced by the pyrolysis of SCB alone. |
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ISSN: | 0960-8524 1873-2976 |
DOI: | 10.1016/j.biortech.2019.03.137 |