Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer

Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective in...

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Veröffentlicht in:Journal of the American Chemical Society 2019-04, Vol.141 (16), p.6462-6467
Hauptverfasser: Nakamura, Takashi, Tsukuda, Shinnosuke, Nabeshima, Tatsuya
Format: Artikel
Sprache:eng
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Zusammenfassung:Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective inclusion of fullerenes (K a(C70)/K a(C60) > 100), utilizing their rigid scaffolds.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.9b00171