Sulfation made simple: a strategy for synthesising sulfated molecules

Sulfation made simple: a strategy for synthesising sulfated molecules

The study of organosulfates is a burgeoning area in biology, yet there are significant challenges with their synthesis. We report the development of a tributylsulfoammonium betaine as a high yielding route to organosulfates. The optimised reaction conditions were interrogated with a diverse range of...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-04, Vol.55 (30), p.4319-4322
Hauptverfasser: Gill, Daniel M, Male, Louise, Jones, Alan M
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Amino acids
Crystal structure
Crystallography
Natural products
Sulfation
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Zusammenfassung:The study of organosulfates is a burgeoning area in biology, yet there are significant challenges with their synthesis. We report the development of a tributylsulfoammonium betaine as a high yielding route to organosulfates. The optimised reaction conditions were interrogated with a diverse range of alcohols, including natural products and amino acids.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc01057b