Cu(II)-Mediated N–H and N‑Alkyl Aryl Amination and Olefin Aziridination

Cu(II)-Mediated N–H and N‑Alkyl Aryl Amination and Olefin Aziridination

Cu­(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh2 catalysts and, in some instances, display important differences with comparable Rh2- and Fe-supported reactions.

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Veröffentlicht in:Organic letters 2019-03, Vol.21 (6), p.1926-1929
Hauptverfasser: Munnuri, Sailu, Anugu, Raghunath Reddy, Falck, John R
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemical synthesis
Alkenes - chemistry
Amination
Aziridines - chemical synthesis
Aziridines - chemistry
Catalysis
Copper - chemistry
Molecular Structure
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Zusammenfassung:Cu­(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh2 catalysts and, in some instances, display important differences with comparable Rh2- and Fe-supported reactions.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.9b00586