Mg-Mg-bonded compounds with N,N'-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Mg-Mg-bonded compounds with N,N'-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N'-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N'-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectrosc...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2019-02, Vol.48 (7), p.2295-2299
Hauptverfasser: Ma, Meimei, Wang, Huanhuan, Wang, Juju, Shen, Lingyi, Zhao, Yanxia, Xu, Wen-Hua, Wu, Biao, Yang, Xiao-Juan
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Crystallography
Dipping
Fluorescence
Ligands
NMR
Nuclear magnetic resonance
Organic chemistry
Phenanthrene
Phenylenediamine
Portable document format
X-ray diffraction
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Zusammenfassung:Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N'-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N'-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt00028c