Amide-Directed Cobalt(III)-Catalyzed C–H Amidation of Ferrocenes

Amide-Directed Cobalt(III)-Catalyzed C–H Amidation of Ferrocenes

The amide-directed cobalt­(III)-catalyzed C–H amidation of ferrocene carboxamides using 1,4,2-dioxazol-5-ones as robust and efficient amidating reagents has been developed. This reaction proceeds efficiently under mild reaction conditions with good functional group tolerance, providing expedient acc...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2019-02, Vol.21 (4), p.951-954
Hauptverfasser: Huang, Dan-Ying, Yao, Qi-Jun, Zhang, Shuo, Xu, Xue-Tao, Zhang, Kun, Shi, Bing-Feng
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The amide-directed cobalt­(III)-catalyzed C–H amidation of ferrocene carboxamides using 1,4,2-dioxazol-5-ones as robust and efficient amidating reagents has been developed. This reaction proceeds efficiently under mild reaction conditions with good functional group tolerance, providing expedient access to a broad range of ferrocenes containing a nitrogen group on the Cp ring.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.8b03938