Assembly of porphyrin-based uranium organic frameworks with (3,4)-connected pto and tbo topologies

Assembly of porphyrin-based uranium organic frameworks with (3,4)-connected pto and tbo topologies

Three (3,4)-connected uranyl-organic frameworks (UOFs) with pto and tbo topologies were synthesized. The UOF with a pto net possesses a 2-fold interpenetrating network and exhibits 2D interconnected channels. The UOF with a tbo net is constructed from two types of ultralarge nanocages. All these com...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2019-02, Vol.48 (5), p.1595-1598
Hauptverfasser: Shao, Lang, Zhai, Fuwan, Wang, Yanlong, Yue, Guozong, Li, Yingru, Chu, Mingfu, Wang, Shuao
Format: Artikel
Sprache:eng
Schlagworte:
Cation exchanging
Cationic dyes
Crystallography
Topology
Uranium
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Zusammenfassung:Three (3,4)-connected uranyl-organic frameworks (UOFs) with pto and tbo topologies were synthesized. The UOF with a pto net possesses a 2-fold interpenetrating network and exhibits 2D interconnected channels. The UOF with a tbo net is constructed from two types of ultralarge nanocages. All these compounds can efficiently remove large cationic dye crystal violet (CV) through a cation exchange mechanism.
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt04585b