Spin dephasing in the Gaussian local phase approximation

The Brownian motion of spins diffusing in an inhomogeneous magnetic field created by susceptibility effects is considered. Applying the correct form of the Gaussian approximation, the method allows calculating the local magnetization as well as the free induction decay for all diffusion regimes. The...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 2018-12, Vol.149 (24), p.244201-244201
Hauptverfasser: Ziener, C. H., Kampf, T., Schlemmer, H.-P., Buschle, L. R.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The Brownian motion of spins diffusing in an inhomogeneous magnetic field created by susceptibility effects is considered. Applying the correct form of the Gaussian approximation, the method allows calculating the local magnetization as well as the free induction decay for all diffusion regimes. The phase accumulated during the diffusional motion is treated by an averaging over all possible trajectories in terms of the Gaussian local phase approximation. Predictions of the Gaussian local phase approximation are compared with the Gaussian phase approximation for diffusion in a constant gradient in a slab, a cylinder, and a sphere. The Gaussian local phase approximation, thereby, shows several advantages compared to the Gaussian phase approximation: it is also valid in the static dephasing regime, predicts correctly both transverse components of the magnetization, and yields information about the local magnetization.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.5050065