Two‐Terminal Multibit Optical Memory via van der Waals Heterostructure

2D van der Waals (vdWs) heterostructures exhibit intriguing optoelectronic properties in photodetectors, solar cells, and light‐emitting diodes. In addition, these materials have the potential to be further extended to optical memories with promising broadband applications for image sensing, logic gates, and synaptic devices for neuromorphic computing. In particular, high programming voltage, high off‐power consumption, and circuital complexity in integration are primary concerns in the development of three‐terminal optical memory devices. This study describes a multilevel nonvolatile optical memory device with a two‐terminal floating‐gate field‐effect transistor with a MoS2/hexagonal boron nitride/graphene heterostructure. The device exhibits an extremely low off‐current of ≈10−14 A and high optical switching on/off current ratio of over ≈106, allowing 18 distinct current levels corresponding to more than four‐bit information storage. Furthermore, it demonstrates an extended endurance of over ≈104 program–erase cycles and a long retention time exceeding 3.6 × 104 s with a low programming voltage of −10 V. This device paves the way for miniaturization and high‐density integration of future optical memories with vdWs heterostructures. A two‐terminal optical memory device is proposed via the floating‐gate field‐effect transistor with a MoS2/hexagonal boron nitride (h‐BN)/graphene heterostructure. By applying successive pulses of source–drain voltage and light illumination to the device, the MoS2 channel is efficiently switched between off‐ and on‐states. Moreover, the state of MoS2 can be preserved for a prolonged period of time.