Surface enhanced resonant Raman scattering in hybrid MoSe2@Au nanostructures

We report on the surface enhanced resonant Raman scattering (SERRS) in hybrid MoSe2@Au plasmonic-excitonic nanostructures, focusing on the situation where the localized surface plasmon resonance of Au nanodisks is finely tuned to the exciton absorption of monolayer MoSe2. Using a resonant excitation...

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Veröffentlicht in:Optics express 2018-10, Vol.26 (22), p.29411-29423
Hauptverfasser: Abid, Inès, Chen, Weibing, Yuan, Jiangtan, Najmaei, Sina, Peñafiel, Emil C, Péchou, Renaud, Large, Nicolas, Lou, Jun, Mlayah, Adnen
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Sprache:eng
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Zusammenfassung:We report on the surface enhanced resonant Raman scattering (SERRS) in hybrid MoSe2@Au plasmonic-excitonic nanostructures, focusing on the situation where the localized surface plasmon resonance of Au nanodisks is finely tuned to the exciton absorption of monolayer MoSe2. Using a resonant excitation, we investigate the SERRS in MoSe2@Au and the resonant Raman scattering (RRS) in a MoSe2@SiO2 reference. Both optical responses are compared to the non-resonant Raman scattering signal, thus providing an estimate of the relative contributions from the localized surface plasmons and the confined excitons to the Raman scattering enhancement. We determine a SERRS/RRS enhancement factor exceeding one order of magnitude. Furthermore, using numerical simulations, we explore the optical near-field properties of the hybrid MoSe2@Au nanostructure and investigate the SERRS efficiency dependence on the nanodisk surface morphology and on the excitation wavelength. We demonstrate that a photothermal effect, due to the resonant plasmonic pumping of electron-hole pairs into the MoSe2 layer, and the surface roughness of the metallic nanostructures are the main limiting factors of the SERRS efficiency.
ISSN:1094-4087
DOI:10.1364/OE.26.029411