Multicolor Emission from Non‐conjugated Polymers Based on a Single Switchable Boron Chromophore

Multicolor emissive and responsive materials are highly attractive owing to their potential applications in various fields, and polymers are preferred for their good processability and high stability. Herein, we report a series of new polymers based on a methacrylate monomer containing a switchable boron chromophore. In spite of their unconjugated nature, interestingly, the homopolymers from this monomer display rare multicolor fluorescence in solution that is highly dependent on the degree of polymerization (DP). With an increasing DP, the local concentration of the chromophore increases, leading to a higher propensity for switching the blue‐emitting tricoordinate boron chromophore to the red‐emitting tetracoordinate one. The homopolymers also display temperature‐ and solvent‐dependent emission color change. Furthermore, pure white‐light emission could be achieved in various solvents by precisely tuning the homopolymer molecular weight, or in films/solid state by copolymerizing the emissive boron monomer with non‐emissive monomers in an appropriate ratio. Multicolor emissive polymers: Multicolor emission was achieved in polymers that contain a switchable boron chromophore and a methacrylate backbone. The molecular weight and degree of polymerization provide the key driving force for the switching of three‐coordinate boron units to four‐coordinate ones in the polymer, and for the emission transition from blue to white and then red.