Electrochemical cobalt-catalyzed C-H or N-H oxidation: a facile route to synthesis of substituted oxindoles
Two comparable protocols for the electrochemical cobalt-catalyzed C-H/N-H oxidation have been exploited for the synthesis of substituted oxindoles via radical pathways. The electrochemical cobalt-catalyzed system was demonstrated to be efficient and eco-friendly and avoided the use of stoichiometric...
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Veröffentlicht in: | Organic & biomolecular chemistry 2018-11, Vol.16 (46), p.8917-8921 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Two comparable protocols for the electrochemical cobalt-catalyzed C-H/N-H oxidation have been exploited for the synthesis of substituted oxindoles via radical pathways. The electrochemical cobalt-catalyzed system was demonstrated to be efficient and eco-friendly and avoided the use of stoichiometric oxidants to afford the arylation or alkylation products in good yields at room temperature. |
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ISSN: | 1477-0520 1477-0539 |
DOI: | 10.1039/c8ob02485e |