A molecularly imprinted polymers/carbon dots-grafted paper sensor for 3-monochloropropane-1,2-diol determination
•MIPs/CDs grafted paper-based sensor for selective and sensitive determination of 3-MCPD.•CDs were intercepted in the paper and MIPs was also directly formed on the paper-based sensor.•The composites exhibited high adsorption capacity and excellent selectivity.•This method could be applied for the d...
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Veröffentlicht in: | Food chemistry 2019-02, Vol.274, p.156-161 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •MIPs/CDs grafted paper-based sensor for selective and sensitive determination of 3-MCPD.•CDs were intercepted in the paper and MIPs was also directly formed on the paper-based sensor.•The composites exhibited high adsorption capacity and excellent selectivity.•This method could be applied for the detection of 3-MCPD in soy sauce samples.
3-Monochloropropane-1,2-diol (3-MCPD) is a common food processing contaminant and a simple, rapid, sensitive and low cost monitoring technology is needed due to its potential carcinogenic nature. Carbon dots directly intercepted on filter paper provide high fluorescence intensity and can be adapted for use as a sensor. We synthesized a carbon dot-filter paper in combination with a molecularly imprinted polymeric film to extract 3-MCPD from samples. This grafted paper-based sensor exhibited a high adsorption capacity (68.97 mg g−1), an excellent selectivity (imprinting factor = 4.5) and a low detection limit (0.6 ng mL−1). Recoveries ranged from 97.2% to 105.3% with relative standard deviations |
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ISSN: | 0308-8146 1873-7072 |
DOI: | 10.1016/j.foodchem.2018.08.133 |