Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure

Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure

To combine noncentrosymmetry, large second order nonlinear optical (NLO) susceptibility, deep UV transparency, and phase matchability simultaneously into a single structure is a great challenge. Especially, the relationship between the macrophase matchability and microstructure has been less investi...

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Veröffentlicht in:Journal of the American Chemical Society 2018-10, Vol.140 (43), p.14082-14086
Hauptverfasser: Chen, Jie, Xiong, Lin, Chen, Ling, Wu, Li-Ming
Format: Artikel
Sprache:eng
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Zusammenfassung:To combine noncentrosymmetry, large second order nonlinear optical (NLO) susceptibility, deep UV transparency, and phase matchability simultaneously into a single structure is a great challenge. Especially, the relationship between the macrophase matchability and microstructure has been less investigated. Herein, we report a unique Ba2NaClP2O7 representing the first phase-matchable example of the fresnoite family, which exhibits excellent NLO properties, including short absorption edge (
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.8b10209