In-plane anisotropic and ultra-low-loss polaritons in a natural van der Waals crystal

Polaritons—hybrid light–matter excitations—enable nanoscale control of light. Particularly large polariton field confinement and long lifetimes can be found in graphene and materials consisting of two-dimensional layers bound by weak van der Waals forces 1 , 2 (vdW materials). These polaritons can be tuned by electric fields 3 , 4 or by material thickness 5 , leading to applications including nanolasers 6 , tunable infrared and terahertz detectors 7 , and molecular sensors 8 . Polaritons with anisotropic propagation along the surface of vdW materials have been predicted, caused by in-plane anisotropic structural and electronic properties 9 . In such materials, elliptic and hyperbolic in-plane polariton dispersion can be expected (for example, plasmon polaritons in black phosphorus 9 ), the latter leading to an enhanced density of optical states and ray-like directional propagation along the surface. However, observation of anisotropic polariton propagation in natural materials has so far remained elusive. Here we report anisotropic polariton propagation along the surface of α-MoO 3 , a natural vdW material. By infrared nano-imaging and nano-spectroscopy of semiconducting α-MoO 3 flakes and disks, we visualize and verify phonon polaritons with elliptic and hyperbolic in-plane dispersion, and with wavelengths (up to 60 times smaller than the corresponding photon wavelengths) comparable to those of graphene plasmon polaritons and boron nitride phonon polaritons 3 – 5 . From signal oscillations in real-space images we measure polariton amplitude lifetimes of 8 picoseconds, which is more than ten times larger than that of graphene plasmon polaritons at room temperature 10 . They are also a factor of about four larger than the best values so far reported for phonon polaritons in isotopically engineered boron nitride 11 and for graphene plasmon polaritons at low temperatures 12 . In-plane anisotropic and ultra-low-loss polaritons in vdW materials could enable directional and strong light–matter interactions, nanoscale directional energy transfer and integrated flat optics in applications ranging from bio-sensing to quantum nanophotonics. Observation of the anisotropic propagation of polaritons along the surface of layered, semiconducting α-MoO 3 confirms the existence of this phenomenon in natural materials.