Self-assembly of a redox-active bolaamphiphile into supramolecular vesicles

Self-assembly of a redox-active bolaamphiphile into supramolecular vesicles

The synthesis and self-assembly of a water-soluble bolaamphiphilic cyclopenta[hi]aceanthrylene derivative is described. Self-assembly in aqueous medium leads to the formation of supramolecular vesicles with intense absorption bands over an extended range of the UV/vis spectral region and a narrow HO...

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Veröffentlicht in:Organic & biomolecular chemistry 2018, Vol.16 (38), p.6886-6889
Hauptverfasser: Rothenbühler, Simon, Bösch, Caroline D, Langenegger, Simon M, Liu, Shi-Xia, Häner, Robert
Format: Artikel
Sprache:eng
Schlagworte:
Absorption spectra
Molecular orbitals
NMR
Nuclear magnetic resonance
Self-assembly
Vesicles
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Zusammenfassung:The synthesis and self-assembly of a water-soluble bolaamphiphilic cyclopenta[hi]aceanthrylene derivative is described. Self-assembly in aqueous medium leads to the formation of supramolecular vesicles with intense absorption bands over an extended range of the UV/vis spectral region and a narrow HOMO-LUMO bandgap of 1.65 eV.
ISSN:1477-0520
1477-0539
DOI:10.1039/c8ob02106f