Efficient removal of Chromium(VI) from aqueous solution using chitosan grafted graphene oxide (CS-GO) nanocomposite

The present study involves the adsorption of hexavalent Chromium(Cr(VI)) using chitosan grafted graphene oxide (CS-GO) nanocomposite in batch mode. The CS-GO nanocomposite material was prepared by ultrasonic irradiation technique. The CS-GO adsorbent was characterized by X-ray diffraction (XRD), Fou...

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Veröffentlicht in:International journal of biological macromolecules 2019-01, Vol.121, p.285-292
Hauptverfasser: Samuel, Melvin S., Bhattacharya, Jayanta, Raj, Sankalp, Santhanam, Needhidasan, Singh, Hemant, Pradeep Singh, N.D.
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Sprache:eng
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Zusammenfassung:The present study involves the adsorption of hexavalent Chromium(Cr(VI)) using chitosan grafted graphene oxide (CS-GO) nanocomposite in batch mode. The CS-GO nanocomposite material was prepared by ultrasonic irradiation technique. The CS-GO adsorbent was characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and Tunnelling electron microscopy (TEM), followed by Cr(VI) adsorption studies. The adsorption capacity of 104.16 mg/g was achieved at pH 2.0, in the contact time of 420 min. The adsorption process was described by the pseudo second order kinetic and Langmuir isotherm model. The nano-microstructural investigation validates the successful adsorption of Cr(VI) on CS-GO nanocomposite. The CS-GO material is recyclable up to 10 cycles with the minimum loss in adsorption capacity. •The use of GO-CS for the adsorption of Chromium(VI) was studied.•Langmuir isotherm and pseudo second order rate kinetics describe batch sorption.•High adsorption capacity (104.16 mg/g) in batch study
ISSN:0141-8130
1879-0003
DOI:10.1016/j.ijbiomac.2018.09.170