Modular O2 electroreduction activity in triphenylene-based metal–organic frameworks

Modular O2 electroreduction activity in triphenylene-based metal–organic frameworks

Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal–organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential t...

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Veröffentlicht in:Chemical science (Cambridge) 2018, Vol.9 (29), p.6286-6291
Hauptverfasser: Miner, Elise M, Wang, Lu, Dincă, Mircea
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalytic activity
Chelation
Electrical resistivity
Metal-organic frameworks
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Zusammenfassung:Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal–organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity.
ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc02049c