Inflating face-capped Pd6L8 coordination cages

Inflating face-capped Pd6L8 coordination cages

Tritopic metalloligands were used to form two Pd6L8-type coordination cages. With molecular weights of more than 15 kDa and Pd⋯Pd distances of up to 4.2 nm, these complexes are among the largest palladium cages described to date.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (68), p.9529-9532
Hauptverfasser: Jansze, Suzanne M, Ortiz, Daniel, Farzaneh Fadaei Tirani, Scopelliti, Rosario, Menin, Laure, Severin, Kay
Format: Artikel
Sprache:eng
Schlagworte:
Cages
Inflating
Palladium
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Beschreibung
Zusammenfassung:Tritopic metalloligands were used to form two Pd6L8-type coordination cages. With molecular weights of more than 15 kDa and Pd⋯Pd distances of up to 4.2 nm, these complexes are among the largest palladium cages described to date.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc04870c