Chemical warfare agent simulant DMMP reactive adsorption on TiO2/graphene oxide composites prepared via titanium peroxo-complex or urea precipitation

[Display omitted] •Two undemanding methods were used to prepare TiO2/GO nanocomposites.•GO addition increased adsorption capacity of the composites.•GO addition resulted in an enhanced reactive dissociation of DMMP.•Redox state of GO is crucial parameter for adsorption and degradation. Two water-bas...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of hazardous materials 2018-10, Vol.359, p.482-490
Hauptverfasser: Henych, Jiří, Štengl, Václav, Mattsson, Andreas, Tolasz, Jakub, Österlund, Lars
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:[Display omitted] •Two undemanding methods were used to prepare TiO2/GO nanocomposites.•GO addition increased adsorption capacity of the composites.•GO addition resulted in an enhanced reactive dissociation of DMMP.•Redox state of GO is crucial parameter for adsorption and degradation. Two water-based methods were used to produce TiO2/graphene oxide (GO) nanocomposites with 1 and 2 wt.% GO. Both procedures exclude the use of organometallic precursors, as well as the high-pressure and high-temperature treatments, which facilitate pure and energy efficient synthesis amenable for larger scale synthesis. Nanocomposites with narrow (
ISSN:0304-3894
1873-3336
DOI:10.1016/j.jhazmat.2018.07.095