Quantitative Determination of 1,4-Dioxane and Tetrahydrofuran in Groundwater by Solid Phase Extraction GC/MS/MS
Groundwater contamination by cyclic ethers, 1,4-dioxane (dioxane), a probable human carcinogen, and tetrahydrofuran (THF), a co-contaminant at many chlorinated solvent release sites, are a growing concern. Cyclic ethers are readily transported in groundwater, yet little is known about their fate in...
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Veröffentlicht in: | Environmental science & technology 2006-12, Vol.40 (23), p.7305-7311 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Groundwater contamination by cyclic ethers, 1,4-dioxane (dioxane), a probable human carcinogen, and tetrahydrofuran (THF), a co-contaminant at many chlorinated solvent release sites, are a growing concern. Cyclic ethers are readily transported in groundwater, yet little is known about their fate in environmental systems. High water solubility coupled with low Henry's law constants and octanol−water partition coefficients make their removal from groundwater problematic for both remedial and analytical purposes. A solid-phase extraction (SPE) method based on activated carbon disks was developed for the quantitative deter mination of dioxane and THF. The method requires 80 mL samples and a total of 1.2 mL of solvent (acetone). The number of steps is minimized due to the “in-vial” elution of the disks. Average recoveries for dioxane and THF were 98% and 95%, respectively, with precision, as indicated by the relative standard deviation of |
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ISSN: | 0013-936X 1520-5851 |
DOI: | 10.1021/es0615270 |